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ASME PTC 19.11 2008 R2013

$98.04

ASME PTC 19.11 Steam and Water Sampling, Conditioning, and Analysis in the Power Cycle – Reaffirmed: 2013

Published By Publication Date Number of Pages
ASME 2008 64
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The object of this Code is to specify and discuss the methods and instrumentation for testing boiler makeup and feedwater, steam, and condensate in relation to performance testing as may be required in Performance Test Codes in on-time acceptance testing and continuous performance monitoring. This Code also provides guidance to power-plant management, engineers, chemists, and operators in the design and operation of sampling systems for monitoring of cycle chemistry. The methods and equipment recommended herein may be useful for monitoring other influent and effluent streams of the power plant. Contamination of the steam and water cycle must be at or less than the maximum specified for the performance test before a turbine, condenser, or deaerator performance test is made.

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PDF Pages PDF Title
5 CONTENTS
6 FIGURES
TABLES
NONMANDATORY APPENDICES
7 NOTICE
8 FOREWORD
10 COMMITTEE ROSTER
11 CORRESPONDENCE WITH THE PTC 19.11 COMMITTEE
13 Section 1 Object, Scope, and Application
1-1 OBJECT
1-2 SCOPE
1-3 APPLICATION
1-4 UNCERTAINTY
14 Section 2 Sample Point and Analysis Selection Criteria
2-1 INTRODUCTION
2-2 THERMAL POWER GENERATION CYCLES
2-3 WATER TREATMENT SCHEMES
15 2-2-1 Generalized Fossil Cycle
16 2-4 MAKEUP
2-5 CONDENSATE
2-2-2 Heat Recovery Steam Generator System
17 2-6 POLISHER EFFLUENT
2-7 DEAERATOR INLET
2-8 DEAERATOR OUTLET
2-9 FINAL FEEDWATER OR ECONOMIZER INLET
2-2 Sample Points and Analyses Location
18 2-10 STEAM GENERATOR WATER
2-10.1 Steam Generators on Solids Treatment
2-10.2 Steam Generators on AVT
2-10.3 Steam Generators on OT
2-10.4 BWR Reactor Water
2-11 SATURATED STEAM
2-12 SUPERHEATED STEAM INCLUDING REHEAT
2-13 FEEDWATER HEATER DRAINS
2-14 MOISTURE SEPARATOR REHEATER DRAINS
2-15 ROTOR AIR COOLERS
19 2-16 BIBLIOGRAPHY
20 Section 3 Obtaining the Sample
3-1 INTRODUCTION
3-2 WATER SAMPLING
3-2.1 Sampling Nozzles
3-2.2 Boiler Water Sample
3-3 ISOKINETIC SAMPLING
3-4 SATURATED STEAM
3-4.1 Sampling Nozzles
21 3-2.1 Typical Nozzles for Sampling Water
3-3 Effects of Nonisokinetic Sampling
3-4.1 Typical Single-Port Nozzle
22 3-5 SUPERHEATED STEAM
3-5.1 Introduction
3-5.2 Sampling Nozzles
3-6 BIBLIOGRAPHY
3-7 FURTHER READING
23 Section 4 Transporting the Sample
4-1 INTRODUCTION
4-2 SAMPLE LINE CONSTRUCTION
4-2.1 Valves
4-2.2 Material Selection and Preparation
4-2.3 Installation
4-2.4 Fabrication
24 4-3 DEPOSITION
4-3.1 Sorption of Dissolved Species
4-3.2 Crystallization
4-4 SATURATED STEAM
25 4-4.1 Deposition
4-4.2 Sample Flow Rate
4-4.3 Steam Sample Line Sizing
4-5 SUPERHEATED STEAM
4-5.1 Introduction
4-5.2 Recirculation System
26 4-4.3-1 Recommended Sample Tube Sizes for Pressures ≥ 500 psia (Used with permission – Sentry Equipment Co.)
27 4-6 LIQUID SAMPLES
4-7 BIBLIOGRAPHY
28 4-4.3-2 Recommended Sample Tube Sizes for Pressures ≤ 400 psia (Used with permission – Sentry Equipment Co.)
30 Section 5 Sample Conditioning
5-1 INTRODUCTION
5-2 DEFINITIONS
5-3 MATERIALS
5-4 VALVES AND FITTINGS
5-4.1 Isolation Valves
5-4.2 Pressure Reducers
31 5-4.3 Pressure Regulators
5-4.4 Blowdown Valves
5-4.5 Other Valves
5-4.5.1 Ball Valves.
5-4.5.2 Sample Relief Valves.
5-4.5.3 Cooling Water Valves On Sample Coolers.
5-4.6 Fittings
5-4.7 Thermal Protection Devices
5-5 SAMPLE COOLERS
32 5-6 FLOW METERS
5-7 SAMPLE FILTERS
5-8 PRESSURE AND TEMPERATURE GAGES
5-9 PUMPS
5-10 SAMPLE CONDITIONING METHODOLOGY
5-10.1 Typical Sample Line
5-10.2 Sample Line Flushing
5-10.2.1 Suggested Startup Procedure for Sampling System.
33 5-10.1 Typical Sample Line for High-Pressure Service
34 5-10.3 Establishing and Verifying Sample-Line Flow and Conditioning
5-10.4 Importance of Secondary Cooling
5-10.5 Grab Sampling
35 5-10.6 Analyzer Verification Patch Panel
5-11 BIBLIOGRAPHY
36 Section 6 Sample Analysis and Instrumentation
6-1 INTRODUCTION
6-2 DEFINITIONS
37 6-2.1 Test Method Details
6-2.2 Purity of Water and Reagents
6-2.3 Sample Guidelines
6-2.3.1 Grab Sample Analysis.
6-2.3.2 On-Line Sample Analysis.
6-2.3.3 Time Sharing of Instruments.
38 6-2.3.4 Data Collection.
6-3 ANALYSIS, DEFINITIONS, AND APPLICATIONS
6-3.1 Alkalinity Hydrated
6-3.2 Amines Neutralizing
6-3.3 Ammonia
6-3.4 Carbon Dioxide
39 6-3.5 Chloride
6-3.6 Conductivity
6-3.6.1 Conductivity, Specific.
6-3.1 Alkalinity
6-3.2 Amines (Neutralizing)
6-3.3 Ammonia
6-3.4 Carbon Dioxide
40 6-3.6.2 Conductivity, Cation Acid Conductivity, Hydrogen Cation-Exchanged Conductivity, or Conductivity After Strong Acid-Cation Exchange.
6-3.6.3 Conductivity, Degassed Cation.
6-3.7 Copper
6-3.5 Chloride
6-3.6.1 Specific Conductivity
41 6-3.8 Dissolved Oxygen
6-3.9 Hydrazine
6-3.6.2 Cation Conductivity
6-3.6.3 Degassed Cation Conductivity
6-3.7 Copper
6-3.8 Dissolved Oxygen
42 6-3.10 Hydrogen
6-3.11 Ion Chromatography
6-3.12 Iron
6-3.13 Morpholine
6-3.9 Hydrazine
6-3.10 Hydrogen
43 6-3.14 Organic Anions
6-3.15 ORP
6-3.16 Oxygen Scavengers
6-3.11 Ion Chromatography
6-3.12 Iron
6-3.14 Organic Anions
44 6-3.17 pH
6-3.18 Phosphate
6-3.19 Reducing Agents
6-3.15 Oxidation-Reduction Potential (ORP)
6-3.16 Oxygen Scavengers (Reducing Agents)
6-3.17 pH
45 6-3.20 Silica
6-3.21 Sodium
6-3.22 Sulfate
6-3.23 Total Organic Carbon TOC
6-3.24 Trace Metals
6-3.25 Turbidity
6-3.18 Phosphate
6-3.20 Silica
46 6-4 OTHER METHODS
6-4.1 Sampling of Metals and Metallic Oxides
6-3.21 Sodium
6-3.22 Sulfate
6-3.23 Total Organic Carbon (TOC)
6-3.25 Turbidity
47 6-4.1.1 Sampling.
6-4.1.2 Summary of Methods for Metals Using Grab Samples.
6-4.1.2.1 Iron.
6-4.1.2.2 Copper.
6-4.1.2.3 Nickel.
6-4.1.2.4 Chromium.
6-4.1.2.5 Zinc.
6-4.1.2.6 Aluminum.
6-4.1.2.7 Lead.
6-4.1.2.8 All Metals.
48 6-4.1.3 Integrated Sampling for Corrosion Products.
6-5 BIBLIOGRAPHY
49 Section 7 Data Acquisition and Data Analysis
7-1 INTRODUCTION
7-2 PURPOSE OF DATA AND DATA STORAGE
7-2.1 Trending and Day-to-Day Control
7-2.2 Warranty
7-2.3 Root Cause Analysis
7-3 DATA QUALITY
7-3.1 Calibration and Validation
7-3.1.1 Calibration.
7-3.1.2 Validation.
7-3.1.3 Annotation of Out-of-Spec Data.
7-3.1.4 Instruments on Several Samples.
7-4 DATA STORAGE ISSUES
7-4.1 Complementary Data Needs
50 7-4.2 Recording Frequency
7-4.3 Compression
7-4.4 Retention Time
7-4.5 Archives for Nonelectronic Data
7-4.5.1 Logs.
7-4.5.2 Physical Archives.
7-4.6 Retrievability and Searchability
51 A Leakage Detection and Measurement
A-1 INTRODUCTION
A-1.1 General
A-1.2 Cooling Water Leaks
A-1.3 Air In-Leakage
A-1.4 Test Results
A-2 COOLING WATER IN-LEAKAGE
A-2.1 General
52 A-2.2 On-Line Methods
A-2.2.1
A-2.2.2
A-2.3 Differential Pressure Methods Vacuum
A-2.3.1
A-2.3.2
A-2.3.3
A-2.3.4
A-2.4 Off-Line Methods
A-2.4.1 Hydrostatic Pressure Method.
A-2.4.2 Fluorescent-Tracer Method.
53 A-3 CONDENSER AIR IN-LEAKAGE
A-3.1 General
A-3.2 Limits
A-3.3 Detection/Location
A-4 DETECTING/LOCATING LEAKS IN THE CYCLE
A-4.1 General
54 A-4.2 Classification of Leaks
A-4.3 Condenser Leak
A-4.4 Detection of Visible Leaks
A-4.5 Detection of Liquid In-Leakage
55 A-4.6 Detection of Air In-Leakage
A-4.7 Detection of Leaks in Boiler Tubes
A-4.8 Locating Leaks
56 A-4.9 Sealing Leaks
A-5 BIBLIOGRAPHY
A-6 FURTHER READING
57 B Throttling Calorimeter
B-1 GENERAL
B-2 FURTHER READING
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ASME PTC 19.11 2008 R2013
$98.04