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BS EN 13725:2022 – TC

$280.87

Tracked Changes. Stationary source emissions. Determination of odour concentration by dynamic olfactometry and odour emission rate

Published By Publication Date Number of Pages
BSI 2022 316
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This document specifies a method for the objective determination of the odour concentration of a gaseous sample using dynamic olfactometry with human assessors. The standard also specifies a method for the determination of the emission rate of odours from stationary sources, in particular: – point sources (conveyed or ducted emissions); – active area sources (e.g. biofilters); – passive sources. The primary application of this standard is to provide a common basis for evaluation of odour emissions. When this document is used for the determination of the odour concentration or the odour emission rate of stationary source emissions, the other relevant European Standards concerning stationary source emissions apply, in particular EN 15259 and EN 16911-1, especially when measurements have to be in compliance with the relevant European Directives concerning industrial air emissions. Even so, the analysis/quantification step of the measurement method described in this document (i.e. the determination of the odour concentration of an odorous gas sample, without respect to the origin of the sample itself) can be fully applied in many cases not related with industrial emission sources (e.g. the measurement of the mass concentration at the detection threshold of pure odorous substances, the determination of effectiveness of deodorizing systems for indoor air). In those latter cases, the requirements in this document concerning the measurement planning and the sampling of stationary sources can be ignored or adapted. This document is applicable to the measurement of odour concentration of pure substances, defined odorant compounds and undefined mixtures of odorant volatiles in air or nitrogen, using dynamic olfactometry with a panel of human assessors being the sensor. The unit of measurement is the European odour unit per cubic metre: ouE/m3. The odour concentration is measured by determining the dilution factor required to reach the detection threshold. The odour concentration at the detection threshold is by definition 1 ouE/m3. The odour concentration is then expressed in terms of multiples of the detection threshold. The range of measurement is typically from 101 ouE/m3 to 107 ouE/m3 (including pre dilution). The field of application of this document includes: – the measurement of the mass concentration at the detection threshold of pure odorous substances in g/m3; – the determination of the EROM value of odorants, in mol; – the measurement of the odour concentration of mixtures of odorants in ouE/m3; – the measurement of the emission rate of odorous emissions from point sources, active area sources and passive area sources, including pre dilution during sampling; – the sampling of odorous gases from emissions of high humidity and temperature (up to 200 °C); – the determination of effectiveness of end-of-pipe mitigation techniques used to reduce odour emissions. The determination of odour emissions requires measurement of gas velocityto determine the gas volume flow rate. The field of application of this document does not include: – the measurement of odours potentially released by particles of odorous solids or droplets of odorous fluids suspended in emissions; – the measuring strategy to be applied in case of variable emission rates; – the measurement of the relationship between odour stimulus and assessor response above detection threshold (perceived intensity); – measurement of hedonic tone (or (un)pleasantness) or assessment of annoyance potential; – direct measurement of odour exposure in ambient air. For this measurement purpose, field panel methods exist which are the subject of CEN standard EN 16841-1, Ambient Air – Determination of odour in ambient air by using field inspection – Grid method; – direct olfactometry, including field olfactometry; – static olfactometry; – measurement of odour recognition thresholds; – measurement of odour identification thresholds. …..

PDF Catalog

PDF Pages PDF Title
1 30454152
191 A-30453629
192 National foreword
197 European foreword
198 1 Scope
199 2 Normative references
3 Terms and definitions
200 3.1 Terms and definitions for olfactometry
205 3.2 Terms and definitions for sampling
208 3.3 Terms and definitions for metrology and statistics
213 4 Symbols and abbreviated terms
215 5 Principle of method
5.1 Odour measurement: odorant gas sampling and odour analysis
5.2 Odorant gas sampling
216 5.3 Determination of odour concentration
5.3.1 General principle of odour concentration measurement
217 5.3.2 Procedure for establishing a robust estimated value of the secondary reference odour mass (SROM)
218 6 Apparatus and materials
6.1 General properties of materials
6.2 Sampling equipment
6.2.1 General
219 6.2.2 Materials for sampling equipment
6.2.3 Cleaning and re-use of sampling equipment
6.3 Sample container
6.3.1 Materials for sample container (bags)
220 6.3.2 Testing of sample containers
6.3.3 Cleaning and re-use of sample containers
6.4 Gases
6.4.1 Neutral gas
221 6.4.2 Odorant reference materials
6.4.3 Reference material for calibration of dilution apparatus (olfactometer)
222 6.5 Dilution apparatus
6.5.1 Construction of the olfactometer
6.5.2 Instrumental dilution range of olfactometer
6.5.3 Interface between nose and olfactometer
223 6.5.4 Calibration procedure
6.6 Environment for observations by assessors
6.6.1 Olfactometry room
224 6.6.2 Air conditioning for the olfactometry room
6.7 Panel
6.7.1 Code of behaviour for assessors and panel members
225 6.7.2 Selection of assessors on individual variability and sensitivity
6.7.3 Monitoring of panel members on individual variability and sensitivity
226 6.7.4 Panel size
7 Performance characteristics and criteria
7.1 General
227 7.2 Accuracy – statistical model
228 7.3 Overall sensory quality requirements
7.3.1 General
7.3.2 Quality criteria for the performance within one laboratory
231 7.3.3 Assessment of precision between laboratories (reproducibility) using environmental samples
7.4 Quality requirements for dilution apparatus
7.4.1 General
232 7.4.2 Quality criteria for the performance of dilution apparatus
233 7.4.3 Quality criterion for instability of dilution apparatus
234 8 Measurement objective and measurement plan
8.1 General
8.2 Preliminary investigation
235 8.3 Measurement plan
9 Measurement procedure
9.1 Sampling
9.1.1 Health and safety issues during sampling
9.1.2 Sampling for delayed olfactometry
236 9.1.3 Sample collection method
237 9.1.4 Pre-dilution during sampling
239 9.1.5 Transport and storage of odorant gas samples before analysis
9.1.6 Sampling strategy
241 9.2 Sampling of a point source
9.2.1 Sampling equipment
9.2.2 Measurement section and measurement site
9.2.3 Volume flow rate measurement
9.3 Sampling of area sources
9.3.1 General
242 9.3.2 Sampling of active area sources
246 9.4 Olfactometric analysis
9.4.1 Modes of presentation and choice
9.4.2 Evaluation time and inter-stimulus time
247 9.4.3 Number and order of presentations
9.4.4 Initial determination of presentation series at the start of the measurement
9.5 Occupational safety for sampling personnel, assessors and olfactometry operators
9.5.1 General
248 9.5.2 Toxicity
9.5.3 The panel members
9.5.4 The olfactometry operators
249 9.5.5 The sampling technicians
251 9.6 Validation and calculation of results
9.6.1 Calculation of odour concentration of a sample from a set of panel member responses
252 9.6.2 Calculation of odour flow from odour concentration and volume flow rate
9.6.3 Calculation of odour abatement efficiency
253 10 Quality assurance and quality control procedures
10.1 Field blank
254 10.2 Measurement uncertainty
10.2.1 General
255 10.2.2 Estimation of the within-laboratory uncertainty
259 10.3 Determination of the limit of detection (LoD) and the limit of quantification (LoQ)
261 11 Measurement records and report
11.1 General
11.2 Records and reporting for emission sampling
262 11.3 Records and reporting for odour concentration measurement
264 Bibliography
266 Annex A (informative) Physiological principles
270 Annex B (informative) Example of calculation of instrumental accuracy and instability
273 Annex C (informative) Example of calculation of odour measurements within one laboratory
275 Annex D (informative) Example of calculations for panel selection
277 Annex E (informative) Example of the calculation of the odour concentration from a set of panel member responses
280 Annex F (informative) Example of the calculation used to determine the number of odour concentration measurements required to achieve a defined precision
283 Annex G (informative) Example of the calculation used to determine the number of odour concentration measurements required to determine a difference between two means
288 Annex H (informative) Example of the calculation of the odour flow rate (standard conditions) for a wet emission
289 Annex I (informative) Example of the calculation of an SROM value for a new defined odorant from an EROM comparison
297 Annex J (informative) Example of the calculation of measurement uncertainty
305 Annex K (informative) Dynamic dilution apparatus for sampling
308 Annex L (informative) Considerations for the interpretation of the odour concentration concept for air quality management
309 Annex M (informative) Sampling of passive area sources
311 Annex N (informative) Significant technical changes
BS EN 13725:2022 - TC
$280.87