BS EN 15721:2013
$142.49
Ethanol as a blending component for petrol. Determination of higher alcohols, methanol and other impurities. Gas chromatographic method
| Published By | Publication Date | Number of Pages |
| BSI | 2013 | 26 |
This European Standard specifies a gas chromatographic method for ethanol, in which higher alcohols (propan-1-ol, butan-1-ol, butan-2-ol, 2-methylpropan-1-ol (isobutanol), 2-methylbutan-1-ol, and 3-methylbutan-1-ol) from 0,1 % up to 2,5 % (m/m), methanol from 0,1 % up to 3 % (m/m) and other impurities, in the range from 0,1 % up to 2 % (m/m) are determined.
Impurities are all the compounds not attributed to the groups of higher alcohols or methanol.
NOTE 1 The European ethanol blending component specification[1] sets a limit for the combined result of ethanol + higher alcohols, not the ethanol content itself.
Due to possible interferences, the method is not applicable to denatured ethanol samples.
Water, if present in the sample, is not included in this analysis, because a signal for water is not visible in the chromatogram. Therefore, if “alcohol content” is called up in a specification, water needs to be considered separately in the calculations.
NOTE 2 For the purposes of this European Standard, the term “% (m/m)” is used to represent the mass fraction (ω).
PDF Catalog
| PDF Pages | PDF Title |
|---|---|
| 7 | 1 Scope 2 Normative references 3 Principle 4 Reagents and materials |
| 8 | 5 Apparatus |
| 9 | 6 Sampling |
| 10 | 7 Procedure 7.1 General 7.2 General considerations for preparation and handling of solutions 7.3 Preparation of solutions for Procedure A 7.3.1 Calibration stock solution (E) for Procedure A |
| 11 | 7.3.2 Internal standard stock solution (ES) for Procedure A 7.3.3 Calibration solution (FS1) for Procedure A 7.3.4 Preparation of sample (S) for Procedure A 7.4 Preparation of solutions for Procedure B 7.4.1 Calibration stock solution (E) for Procedure B |
| 12 | 7.4.2 Internal standard stock solution (ES) for Procedure B 7.4.3 Calibration solution (FS1) for Procedure B 7.4.4 Preparation of sample (S) for Procedure B 7.5 Determination 7.5.1 Gas chromatograph analysis conditions |
| 13 | 7.5.2 Determination of response factors |
| 14 | 7.5.3 Recording the chromatogram 7.5.4 Performance checks 8 Calculation 8.1 Content of individual compounds 8.2 Calculation of group contents |
| 15 | 8.3 Expression of results 9 Precision 9.1 General 9.2 Repeatability 9.3 Reproducibility |
| 16 | 10 Test report |
| 17 | Annex A (informative) Examples of chromatograms |
