BSI 21/30427377 DC:2021 Edition
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BS EN ISO 3146. Plastics. Determination of melting behaviour (melting temperature or melting range) of semi-crystalline polymers by capillary tube and polarizing-microscope methods
Published By | Publication Date | Number of Pages |
BSI | 2021 | 17 |
This document specifies two methods for evaluating the melting behaviour of semi-crystalline polymers.
Melting temperatures determined by the different methods usually differ by several kelvins for the reasons explained in the introduction.
Method A: Capillary tube
This method is based on the changes in shape of the polymer. It is applicable to all semi-crystalline polymers and their compounds.
Method A can also be useful for the evaluation of the softening of non-crystalline solids.
Method B: Polarizing microscope
This method is based on changes in the optical properties of the polymer. It is applicable to polymers containing a birefringent crystalline phase. It may not be suitable for plastics compounds containing pigments and/or other additives which could interfere with the birefringence of the polymeric crystalline zone.
Another method applicable to semi-crystalline polymers is described in ISO 11357-3, Plastics — Differential scanning calorimetry (DSC) — Part 3: Determination of temperature and enthalpy of melting and crystallization.