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ASTM-D6296 2008

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D6296-98(2008) Standard Test Method for Total Olefins in Spark-ignition Engine Fuels by Multidimensional Gas Chromatography

Published By Publication Date Number of Pages
ASTM 2008 8
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ASTM D6296-98-Reapproved2008

Historical Standard: Standard Test Method for Total Olefins in Spark-ignition Engine Fuels by Multidimensional Gas Chromatography

ASTM D6296

Scope

1.1 This test method provides for the quantitative determination of total olefins in the C4 to C10 range in spark-ignition engine fuels or related hydrocarbon streams, such as naphthas and cracked naphthas. Olefin concentrations in the range from 0.2 to 5.0 liquid-volume % or mass %, or both, can be determined directly on the as-received sample whereas olefins in samples containing higher concentrations are determined after appropriate sample dilution prior to analysis.

1.2 This test method is applicable to samples containing alcohols and ethers; however, samples containing greater than 15 % alcohol must be diluted. Samples containing greater than 5.0 % ether must also be diluted to the 5.0 % or less level, prior to analysis. When ethyl-tert-butylether is present, only olefins in the C4 to C9 range can be determined.

1.3 This test method can not be used to determine individual olefin components.

1.4 This test method can not be used to determine olefins having higher carbon numbers than C10.

Note 1ā€”Precision was determined only on samples containing MTBE and ethanol.

1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

Keywords

gas chromatography; gasoline; multidimensional gas chromatography; olefins; spark-ignition engine fuels; Automotive engine fuels/oils; Gas chromatography (GC)–petroleum products; Multi-dimensional gas chromatography; Olefins content; Total olefins

ICS Code

ICS Number Code 71.040.50 (Physicochemical methods of analysis)

DOI: 10.1520/D6296-98R08

PDF Catalog

PDF Pages PDF Title
1 Scope
Referenced Documents
Terminology
Summary of Test Method
2 Significance and Use
Interferences
Apparatus
FIG. 1
3 Reagents and Materials
TABLE 1
4 Preparation and Setup of Apparatus
TABLE 2
TABLE 3
TABLE 4
5 Procedure
FIG. 2
TABLE 5
6 Calibration
FIG. 3
7 Calculation
FIG. 4
8 Report
Precision and Bias
Keywords
ASTM-D6296 2008
$40.63