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BS EN ISO 14851:2004:2008 Edition

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Determination of the ultimate aerobic biodegradability of plastic materials in an aqueous medium. Method by measuring the oxygen demand in a closed respirometer

Published By Publication Date Number of Pages
BSI 2008 24
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PDF Pages PDF Title
1 BRITISH STANDARD
2 National foreword
4 Foreword
5 1 Scope
2 Normative references
6 3 Definitions
ultimate aerobic biodegradation
activated sludge
concentration of suspended solids in an activated sludge
biochemical oxygen demand
theoretical oxygen demand
total organic carbon
dissolved organic carbon
lag phase
maximum level of biodegradation
7 biodegradation phase
plateau phase
pre-exposure
pre-conditioning
4 Principle
5 Test environment
8 6 Reagents
6.1 Distilled or deionized water
6.2 Test medium
9 6.3 Pyrophosphate solution
6.4 Carbon dioxide absorber,
10 7 Apparatus
7.1 Closed respirometer,
7.2 Analytical equipment for measuring total organic carbon (TOC) and dissolved organic carbon (DOC)
7.3 Analytical equipment for measuring nitrate and nitrite concentrations
7.4 Centrifuge,
7.5 Analytical balance
7.6 pH meter
8 Procedure
8.1 Test material
8.2 Reference material
11 8.3 Preparation of the inoculum
12 8.4 Test
Table 1 Final distribution of test and reference materials
13 9 Calculation and expression of results
9.1 Calculation
9.2 Expression and interpretation of results
10 Validity of results
14 11 Test report
15 Annex A (informative)
Theoretical oxygen demand (ThOD)
A.1 Calculation of the ThOD
A.2
A.3 Example: Blend of polyethylene/starch/glycerol
Annex B (informative) Correction of BOD values for interference by nitrification
Correction of BOD values for interference by nitrification
B.1 Influence of nitrification
16 B.2 Example
17 Annex C (informative) Principle of a closed manometric respirometer
Principle of a closed manometric respirometer
Figure C.1 Schematic drawing of a manometric respirometer
18 Annex D (informative) Two-phase closed-bottle version of the respirometric test
Two-phase closed-bottle version of the respirometric test
D.1 Principle
D.2 Special apparatus
Incubation bottles:
Oxygen electrode,
Magnetic stirrer or shaking device
D.3 Procedure
19 D.4 Calculation of results
20 Annex E (informative) Example of the determination of a carbon balance
Example of the determination of a carbon balance
E.1 Principle
E.2 Test procedure
E.3 Calculation of the carbon balance
21 E.4 Example: Carbon balance of poly(¶-hydroxybutyrate)
Annex F (informative) Example of a determination of the amount of water-insoluble polymer remaining at th…
Example of a determination of the amount of water-insoluble polymer remaining at th…
22 Annex G (informative) Bibliography
Bibliography
23 Annex ZA (normative)
BS EN ISO 14851:2004
$142.49